 |
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
MSDS for 4-Aminobenzonitrile,99%XINGHUICHEM00128 **** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION **** MSDS Name: 4-Aminobenzonitrile,99% Catalog Numbers: XH00128 Synonyms: 4-Cyanoaniline; P-Aminobenzonitrile; P-Cyanoaniline Company Identification: Changzhou Xinghui Chemical Co., Ltd. Xinqiao town, Changzhou, Jiangsu,China Tel:0086-519-85912897,5920258Fax:0086-519-85910153 E-mail:czxinhe@public.cz.js.cn **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
Hazard Symbols: XN Risk Phrases: 22 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Appearance:white to pale yellow. Warning! Causes respiratory tract irritation. May cause digestive tract irritation. Irritant. Harmful if swallowed. Methemoglobin forming agent. Causes eye and skin irritation. Target Organs: Blood, spleen. Potential Health Effects Eye: Causes moderate eye irritation. Skin: Causes skin irritation. May be absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Effects may be delayed 2 to 4 hours. May form methemoglobin which in sufficient concentration causes cyanosis. Inhalation: Effects may be delayed. May cause cyanosis, characterized by bluish-colored skin. May cause effects similar to those described for ingestion. Causes irritation of the mucous membrane and upper respiratory tract. Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Effects may be delayed. Treat symptomatically and supportively. If cyanosis is severe, intravenous injection of Methylene blue, 1mg/kg of body weight may be of value. For methemoglobinemia, administer oxygen alone or with Methylene blue depending on the methemoglobinemia concentration in the blood. **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Do not ingest or inhale. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits
OSHA Vacated PELs: 4-Aminobenzonitrile: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
**** SECTION 10 - STABILITY AND REACTIVITY **** Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, cyanides. Hazardous Polymerization: Has not been reported. **** SECTION 11 - TOXICOLOGICAL INFORMATION **** RTECS#: CAS# 873-74-5: BX2320000 LD50/LC50:Draize test, rabbit, eye: 100 mg Moderate Oral, mouse: LD50 = 168 mg/kg Oral, rat: LD50 = 283 mg/kg. Carcinogenicity: 4-Aminobenzonitrile - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: No information available. Teratogenicity: No information available. Reproductive Effects: No information available. Neurotoxicity: No information available. Mutagenicity: No information available. Other Studies: Standard Draize Test: Administration into the eye (rabbit) = 100 mg (Moderate). **** SECTION 12 - ECOLOGICAL INFORMATION **** Ecotoxicity: Bacteria: Phytobacterium phosphoreum: EC50 = 0.19 mg/L; 30 min; Microtox test at 15C **** SECTION 13 - DISPOSAL CONSIDERATIONS **** Chemical waste generators must determine whether a discarded chemical is classify as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Part Additionally, waste generators must consult state and local hazardous waste regular ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. **** SECTION 14 - TRANSPORT INFORMATION ****
**** SECTION 15 - REGULATORY INFORMATION **** US FEDERAL TSCA CAS# 873-74-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ) None of the chemicals in this material have an RQ. Section 302 (TPQ) None of the chemicals in this product have a TPQ. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE 4-Aminobenzonitrile is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22Harmful if swallowed. Safety Phrases: S 24/25Avoid contact with skin and eyes. S 36/37/39Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 873-74-5: No information available. United Kingdom Occupational Exposure Limits Canada None of the chemicals in this product are listed on the DSL/NDSL list. This product has a WHMIS classification of D1B, D2B. CAS# 873-74-5 is not listed on Canada's Ingredient Disclosure List. Exposure Limits **** SECTION 16 - ADDITIONAL INFORMATION **** MSDS Creation Date: 28/01/2000update: 28/03/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. |
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|